PREPARATION AND ELECTROCATALYTIC PROPERTIES OF PALLADIUM MICRODEPOSITS INCORPORATED INTO A NAFION FILM

Authors
PODLOVCHENKO BI SMOLIN AV MAKSIMOV YM
Citation
Bi. Podlovchenko et al., PREPARATION AND ELECTROCATALYTIC PROPERTIES OF PALLADIUM MICRODEPOSITS INCORPORATED INTO A NAFION FILM, Russian journal of electrochemistry, 31(10), 1995, pp. 1085-1091
Citations number
26
Categorie Soggetti
Electrochemistry
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
31
Issue
10
Year of publication
1995
Pages
1085 - 1091
Database
ISI
SICI code
1023-1935(1995)31:10<1085:PAEPOP>2.0.ZU;2-K
Abstract
Highly dispersed palladium particles were electrodeposited from PdCl2 + H2SO4 and PdCl2 + HCl solutions in st Nafion film applied on vitreou s carbon. Possible factors responsible for the Nafion film permeabilit y to [PdCl4](2-) anions and impermeability to [Fe(CN)(6)](3-) anions a re discussed. A substantial effect of deposition conditions on the ele ctrocatalytic properties of palladium catalysts was discovered. The ro le of the polymeric matrix in the formation of palladium particles and their behavior in the processes of hydrogen sorption and formic acid electrooxidation is discussed.