Neural pattern recognition was used to analyse the low-energy Auger sp
ectra of a thermally annealed Si/Ni/Si layered structure measured duri
ng the acquisition of a depth profile. The purpose was to gain informa
tion about the chemical state of the elements at the interfaces by pro
cessing the data in a way quite similar to conventional target factor
analysis (TFA). The new approach, however, has some important advantag
es: no standards are required, it is extremely fast and it is fully au
tomatic, In principle, there is only one arbitrary parameter, the vigi
lance parameter rho, which sets a threshold for the level of similarit
y required for assuming two spectra as belonging to the same class of
data. However, the requirement that the optimal value for rho should c
orrespond to the maximal correlation between the experimental data set
and the recalculated spectra makes the system also robust against mis
conclusions based on subjective interpretation of the data set, which
is not always the case in TFA.