Spectrophotometric indices for 18 Galactic globular clusters, obtained
from CCD observations and careful reductions, were used to determine
reliable calibrations on metallicity [Fe/H]. The indices were measured
in the bandpasses adopted by Burnstein et al. (1984). Adding other ob
servations of Burnstein et al. (1984) we obtained our results from an
homogeneous sample of indices for 26 globular clusters. Relations with
indices defined by other Authors and with metallicity photometric ind
ices or parameters were also computed. In each case the relations are
quite satisfactory. Observational data were compared with synthetic in
dices derived from Buzzoni's (1989) models and detailed discussions we
re performed for Mg-2, Fe-52, and H-beta. The observational points see
m to be systematically shifted with respect to the fiducial lines trac
ed by the models. The scenario confirms that a certain degree of oxyge
n enhancement would be necessary to obtain a better agreement between
observed data and theoretical predictions. This enhancement, however,
removes some of the disagreement, but not all of it. The dependence of
the observed Fe-52 and H-beta indices on the metal content for differ
ent HB morphologies was considered. Finally, some results were also di
scussed from a statistical point of view. A principal component analys
is was applied to the index sample to study the number of independent
parameters necessary to reproduce the observations. The whole index se
t is completely consistent with a one-parameter family.