A 25-year (1966-1990) record of measurements of the broad-band direct
solar irradiances performed in Athens, has been utilized to determine
the radiant energy distribution in several spectral bands. Using these
data the year-to-year trend of the time sequences of the mean values
of the irradiation ratios in the various spectral intervals, viz. blue
, green/orange, red, and photosynthetically active radiation (PAR) and
the total direct irradiance for the whole spectrum, are evaluated. Fr
om this trend the following can be concluded: the blue spectral band (
0.380-0.525 mum) decreased from the beginning of the examined period u
ntil the mid-seventies and then increased gradually; the red band (0.6
30-0.710 mum) shows similar trend but opposite in sense. The PAR band
(0.380-0.710 mum) decreased slightly until 1985 and then increases. In
the green/orange band (0.525-0.630 mum) the trend can be considered a
s nearly constant throughout the examined period. This trend of the ir
radiation ratios is related to the aerosol and gaseous pollutant conte
nt of the atmosphere, which probably reflects the urbanization, indust
rialization and heavy traffic conditions of the Athens area, during th
e last three decades.