KINETICS AND MECHANISM OF THE CONVERSION OF METHYLMETHACRYLATE IN RF DISCHARGES

Authors
SHCHEGLOV AN KOVALCHUK AV YURANOVA TI VASILETS VN PONOMAROV AN
Citation
An. Shcheglov et al., KINETICS AND MECHANISM OF THE CONVERSION OF METHYLMETHACRYLATE IN RF DISCHARGES, High energy chemistry, 27(1), 1993, pp. 71-77
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
High energy chemistry → ACNP
ISSN journal
00181439
Volume
27
Issue
1
Year of publication
1993
Pages
71 - 77
Database
ISI
SICI code
0018-1439(1993)27:1<71:KAMOTC>2.0.ZU;2-6
Abstract
Gas chromatography and IR Fourier spectrometry are used to study the c omposition of the stable gaseous products from the dissociation of met hylmethacrylate in rf discharge plasmas (13.6 MHz) in mixtures with ar gon at various discharge powers (10-100 W), residence times in the act ive zone (3.8-30 msec), and pressures of methylmethacrylate (0.66-13.3 Pa) and Ar (66-400 Pa). A kinetic scheme for this plasma chemical pro cess is proposed on the basis of an analysis of the experimental data.