Y. Hayashi et al., INFORMATION-BASED PREDICTION OF THE PRECISION AND EVALUATION OF THE ACCURACY OF THE RESULTS FROM AN ADAPTIVE FILTER, Chemometrics and intelligent laboratory systems, 20(2), 1993, pp. 163-171
This paper demonstrates the prediction of the relative standard deviat
ions of the amplitude estimates for overlapped target and interferant
Gaussian peaks that simulate overlapped spectral responses. The estima
tes for the target (known) peak amplitude are obtained by using an ada
ptive Kalman filter; the estimates for the interferant (unknown) peak
amplitude are obtained by subtraction of the estimated contribution of
the target peak from the overlapped spectrum. Repeated computer simul
ations show that the behavior of the averages and relative standard de
viations of the amplitude estimates for both peaks and for the positio
n of the interferant peak show some similarities as a function of the
peak overlap and the amplitude ratio of the peaks. Given a model for t
he target peak, the relative standard deviations for the areas of both
peaks can be predicted based on the function of mutual information us
ing a single spectrum, without resorting to repeated simulations.