4 NEW POLYACETYLENIC GLUCOSIDES, METHYL BETA-D-GLUCOPYRANOSYL HELIANTHENATE C-F, FROM JERUSALEM-ARTICHOKE (HELIANTHUS-TUBEROSUS L)

Authors
MATSUURA H YOSHIHARA T ICHIHARA A
Citation
H. Matsuura et al., 4 NEW POLYACETYLENIC GLUCOSIDES, METHYL BETA-D-GLUCOPYRANOSYL HELIANTHENATE C-F, FROM JERUSALEM-ARTICHOKE (HELIANTHUS-TUBEROSUS L), Bioscience, biotechnology, and biochemistry, 57(9), 1993, pp. 1492-1498
Citations number
9
Categorie Soggetti
Biology,Agriculture,"Biothechnology & Applied Migrobiology","Food Science & Tenology
Journal title
Bioscience, biotechnology, and biochemistry → ACNP
ISSN journal
09168451
Volume
57
Issue
9
Year of publication
1993
Pages
1492 - 1498
Database
ISI
SICI code
0916-8451(1993)57:9<1492:4NPGMB>2.0.ZU;2-I
Abstract
Four new polyacetylenic glucosides isolated from the leaf of Jerusalem artichoke (Helianthus tuberosus L.) were characterized as methyl beta -D-glucopyranosyl helianthenate C (5), D (6), E (7), and F (8). The ab solute stereochemistry of the glucosyloxymethine was also determined t o be of R configuration by preparing the relative compounds with Sharp less asymmetric epoxidation as the kev step and source of optical acti vity.