STEREOCHEMISTRY AND BIOLOGICAL-ACTIVITY OF METHYL HYDROGEN 3-PHENYL-2,2'-IMINODIPRO-PIONATE PRODUCED BY BOTRYTIS-SQUAMOSA

Authors
NAKASHIMA R HAYASHI N MIZUTANI T UEDA N YAMAMOTO J KIMURA Y
Citation
R. Nakashima et al., STEREOCHEMISTRY AND BIOLOGICAL-ACTIVITY OF METHYL HYDROGEN 3-PHENYL-2,2'-IMINODIPRO-PIONATE PRODUCED BY BOTRYTIS-SQUAMOSA, Bioscience, biotechnology, and biochemistry, 57(9), 1993, pp. 1514-1517
Citations number
4
Categorie Soggetti
Biology,Agriculture,"Biothechnology & Applied Migrobiology","Food Science & Tenology
Journal title
Bioscience, biotechnology, and biochemistry → ACNP
ISSN journal
09168451
Volume
57
Issue
9
Year of publication
1993
Pages
1514 - 1517
Database
ISI
SICI code
0916-8451(1993)57:9<1514:SABOMH>2.0.ZU;2-Q
Abstract
The stereochemistry of 1-methyl hydrogen 3-phenyl-2,2'-iminodipropiona te (BSF-A, 1) was determined to be 2S, 2'S by comparing the spectral d ata of 1 with those of synthetic derivatives. The effects of BSF-A (1) and its analogs on the growth rate of lettuce seedlings were examined . Both diastereomers, 3a (2S, 2'S) and 3b (2S, 2'R), of dimethyl 3-phe nyl-2,2'-iminodipropionate and a regioisomer, 1'-methyl hydrogen 3-phe nyl-2,2'-iminodipropionate (2), exhibited biological activity similar to that of natural product BSF-A (1).