OXIDATION OF 2-METHYLCYCLOHEXANONE AND CYCLOHEXANONE BY DIOXYGEN CATALYZED BY VANADIUM-CONTAINING HETEROPOLYANIONS

Authors
ATLAMSANI A BREGEAULT JM ZIYAD M
Citation
A. Atlamsani et al., OXIDATION OF 2-METHYLCYCLOHEXANONE AND CYCLOHEXANONE BY DIOXYGEN CATALYZED BY VANADIUM-CONTAINING HETEROPOLYANIONS, Journal of organic chemistry, 58(21), 1993, pp. 5663-5665
Citations number
49
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
21
Year of publication
1993
Pages
5663 - 5665
Database
ISI
SICI code
0022-3263(1993)58:21<5663:OO2ACB>2.0.ZU;2-U
Abstract
2-Methylcyclohexanone is oxidized by dioxygen in the presence of H3+n[ PMo12-nVnO40].aq to give 6-oxoheptanoic acid. Solvent effects are stud ied. The same precursors with cyclohexanone in aqueous acetic acid giv e adipic acid as the major product and other dicarboxylic acids by oxi dation of 6-oxohexanoic acid.