SPIN-DEPENDENT UNITARY-GROUP APPROACH TO THE PAULI-BREIT HAMILTONIAN .2. 1ST-ORDER ENERGY-LEVEL SHIFTS DUE TO SPIN-SPIN INTERACTION

Citation
Md. Gould et Js. Battle, SPIN-DEPENDENT UNITARY-GROUP APPROACH TO THE PAULI-BREIT HAMILTONIAN .2. 1ST-ORDER ENERGY-LEVEL SHIFTS DUE TO SPIN-SPIN INTERACTION, The Journal of chemical physics, 99(8), 1993, pp. 5983-5994
Citations number
41
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
99
Issue
8
Year of publication
1993
Pages
5983 - 5994
Database
ISI
SICI code
0021-9606(1993)99:8<5983:SUATTP>2.0.ZU;2-K
Abstract
This paper is a continuation of a previous investigation of the Pauli- Breit Hamiltonian in the framework of the graphical spin-dependent uni tary group approach to many electron systems. The SU(2) tensor form fo r the spin-spin interaction and its corresponding zero spin-shift comp onent are determined explicitly and applied to investigate the first o rder energy level splitting due to the spin-spin interaction, entirely within the context of the unitary group approach. Our results are als o discussed in terms of the unitary group density matrix formalism.