Md. Gould et Js. Battle, SPIN-DEPENDENT UNITARY-GROUP APPROACH TO THE PAULI-BREIT HAMILTONIAN .2. 1ST-ORDER ENERGY-LEVEL SHIFTS DUE TO SPIN-SPIN INTERACTION, The Journal of chemical physics, 99(8), 1993, pp. 5983-5994
This paper is a continuation of a previous investigation of the Pauli-
Breit Hamiltonian in the framework of the graphical spin-dependent uni
tary group approach to many electron systems. The SU(2) tensor form fo
r the spin-spin interaction and its corresponding zero spin-shift comp
onent are determined explicitly and applied to investigate the first o
rder energy level splitting due to the spin-spin interaction, entirely
within the context of the unitary group approach. Our results are als
o discussed in terms of the unitary group density matrix formalism.