Electron energy loss spectra have been performed on C60 vapour, both a
t very low (E(r)=0), and at intermediate residual energies (up to E(r)
=70 eV), along with an angular analysis of the scattered electrons. Be
sides the two strong bands at 3.78 and 4.84 eV, due to dipole-allowed
transitions to 1T1u states, and the pi-pi collective excitation at 6.
1 eV, we have observed a band peaking at 2.26 eV, dominant at low resi
dual energies, corresponding to superimposed transitions to triplet st
ates, and dipole orbitally forbidden states. A new peak, likely to be
of triplet character is observed at 2.96 eV. In contrast with similar
studies on C60 films, we have not found any evidence of the lowest tri
plet state 3T2g at 1.55 eV.