Ab. Attygalle et al., DEFENSE-MECHANISMS OF ANTHROPODS .119. ALKALOIDS OF THE MEXICAN BEAN BEETLE, EPILACHNA-VARIVESTIS (COCCINELLIDAE), Tetrahedron, 49(41), 1993, pp. 9333-9342
Two novel alkaloids, 2-(12-aminotridecyl)-pyrrolidine and its 1-(2-hyd
roxyethyl) derivative, are characterized from extracts of adult Mexica
n bean beetles. These pyrrolidines, together with a previously identif
ied homotropane alkaloid, euphococcinine, account for 90% of the alkal
oids present in this beetle. A number of piperidine derivatives are al
so identified as minor components. The total mixture represents the mo
st complex bouquet of alkaloids reported hitherto from any coccinellid
beetle.