ASSIGNMENT OF RELATIVE AND ABSOLUTE-CONFIGURATION OF ACYCLIC POLYOLS AND AMINOPOLYOLS BY CIRCULAR-DICHROISM - TRENDS FOLLOW FISCHER SUGAR FAMILY TREE

Authors
ZHOU P BEROVA N WIESLER WT NAKANISHI K
Citation
P. Zhou et al., ASSIGNMENT OF RELATIVE AND ABSOLUTE-CONFIGURATION OF ACYCLIC POLYOLS AND AMINOPOLYOLS BY CIRCULAR-DICHROISM - TRENDS FOLLOW FISCHER SUGAR FAMILY TREE, Tetrahedron, 49(41), 1993, pp. 9343-9352
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
49
Issue
41
Year of publication
1993
Pages
9343 - 9352
Database
ISI
SICI code
0040-4020(1993)49:41<9343:AORAAO>2.0.ZU;2-Y
Abstract
Reference CD curves (measured in methylcyclohexane) of a homologous se ries of 1,2-polyols up to pentols derivatized as anthroates at 1-OH an d p-methoxycinnamates at the remaining hydroxyl groups show a systemat ic trend that greatly simplifies assignments of relative and absolute configurations. The same trend also holds for the corresponding 1-amin opolyols, but not for 2-aminopolyols.