RESIDUAL DIPOLAR SPLITTINGS IN C-13-MAS NMR ARISING FROM INTERACTIONSWITH CHLORINE NUCLEI

Authors
HARRIS RK SUNNETCIOGLU MM CAMERON KS RIDDELL FG
Citation
Rk. Harris et al., RESIDUAL DIPOLAR SPLITTINGS IN C-13-MAS NMR ARISING FROM INTERACTIONSWITH CHLORINE NUCLEI, Magnetic resonance in chemistry, 31(10), 1993, pp. 963-965
Citations number
24
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
31
Issue
10
Year of publication
1993
Pages
963 - 965
Database
ISI
SICI code
0749-1581(1993)31:10<963:RDSICN>2.0.ZU;2-X
Abstract
Residual dipolar splittings in C-13 cross-polarization magic-angle spi nning spectra arising from coupling to chlorine nuclei are reported fo r the three chloroacetanilide isomers, using several spectrometers. At medium to high magnetic field doublets are seen for C-Cl carbon reson ances. Perturbation theory explains the appearance of the spectra qual itatively but is inadequate quantitatively.