The protective properties of eight high performance commercial multila
yer organic coatings for aeronautical use (based on polyurethane, epox
y and polyurethane-compatible epoxy resins) on anodised 2024-T3 Al all
oy were evaluated in neutral aerated 3.5% NaCl aqueous solution using
the electrochemical impedance spectroscopy (EIS) technique. The invest
igation was performed on specimens supplied and prepared from Alenia i
n accordance with their technical specifications. Results obtained in
this paper show that all coating systems exhibit excellent protective
properties even after prolonged immersion in the test solution (one ye
ar). Although the dielectric properties of all multilayer coatings are
quite similar, EIS was proved to be able to discriminate among them,
making possible a rank of these protective systems to prevent or to re
duce corrosion. Capacitance measurements performed on the same coating
s allow their behaviour to be forecasted.