We perform Shell Model Monte Carlo calculations to study pair correlat
ions in the ground states of N = Z nuclei with masses A = 48-60. We fi
nd that T = 1, J(pi) = 0(+) proton-neutron correlations play an import
ant, and even dominant role, in the ground states of odd-odd N = Z nuc
lei, in agreement with experiment. By studying pairing in the ground s
tales of Fe-52-58, we observe that the isovector proton-neutron correl
ations decrease rapidly with increasing neutron excess. In contrast, b
oth the proton, and trivially the neutron correlations increase as neu
trons are added, We also study the thermal properties and the temperat
ure dependence of pair correlations for Mn-50 and Fe-52 as exemplars o
f odd-odd and even-even N = Z nuclei. While for Fe-52 results are simi
lar to those obtained for other even-even nuclei in this mass range, t
he properties of Mn-50 at low temperatures are strongly influenced by
isovector neutron-proton pairing. In coexistence with these isovector
pair correlations, our calculations also indicate an excess of isoscal
ar proton-neutron pairing over the mean-field values. The isovector ne
utron-proton correlations rapidly decrease with temperatures and vanis
h for temperatures above T = 700 keV, while the isovector correlations
among like-nucleons persist to higher temperatures. Related to the qu
enching of the isovector proton-neutron correlations, the average isos
pin decreases from 1, appropriate for the ground state, to 0 as the te
mperature increases.