CONVENIENT SYNTHESIS AND REACTIVITY OF DINITROSYLBIS (TRIPHENYLPHOSPHINE) RUTHENIUM

Citation
Bc. Paul et al., CONVENIENT SYNTHESIS AND REACTIVITY OF DINITROSYLBIS (TRIPHENYLPHOSPHINE) RUTHENIUM, Journal of coordination chemistry, 28(3-4), 1993, pp. 245-249
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00958972
Volume
28
Issue
3-4
Year of publication
1993
Part
A
Pages
245 - 249
Database
ISI
SICI code
0095-8972(1993)28:3-4<245:CSAROD>2.0.ZU;2-M
Abstract
[Ru(NO)2(PPh3)2] has been synthsized by three convenient methods. Its reactivity has been studied with HX (X = Cl, Br or I) and with neutral mono- and bidentate nitrogen ligands. The products obtained have the compositions [RuX3(NO)(PPh3)2] (X = Cl, Br, or I) and [Ru(NO)(NO2)(OH) 2L] (L = py, bipy or phen), respectively.