In order to contrast the Huckel molecular orbital theory (HMO) with a
simple valence bond theory (Heisenberg-Dirac model), which are two opp
osite asymptotic limit cases of the Hubbard model, Hubbard problems ha
ve been solved for four sites systems with four electrons. The Huckel-
Hubbard correlation diagrams, where employs a parameter: U/t, have bee
n obtained for these system. From correlation diagrams some interested
results have been deduced in detail.