Recent investigations of zinc samples exposed in atmospheric field and
laboratory exposure conditions have provided evidence of two newly di
scovered zinc chlorohydroxosulfates as corrosion products. In order to
obtain a better understanding, detailed studies have been undertaken
to characterize the formation and growth of both zinc chlorohydroxosul
fates. One of them is observed mainly in marine environments, the othe
r mainly in industrial environments, and the present study aims at des
cribing the formation of sodium zinc chlorohydroxosulfate, NaZn4Cl(OH)
6SO4.6H2O, in a marine atmosphere. A field exposure program has been p
erformed with emphasis on short exposure periods and detailed characte
rization of initially formed layers of corrosion products by means of
a multianalytical approach. A reaction sequence is identified which is
consistent with all methods used. It involves the consecutive formati
on of three structurally related phases, namely zinc hydroxycarbonate
as the initial phase, zinc hydroxychloride as the intermediate phase a
nd sodium zinc chlorohydroxosulfate as the final phase.