A NEW SYNTHESIS OF 3-DEOXY-D-MANNO-2-OCTULOSONIC ACID (KDO)

Citation
P. Coutrot et al., A NEW SYNTHESIS OF 3-DEOXY-D-MANNO-2-OCTULOSONIC ACID (KDO), Tetrahedron letters, 34(32), 1993, pp. 5089-5092
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
32
Year of publication
1993
Pages
5089 - 5092
Database
ISI
SICI code
0040-4039(1993)34:32<5089:ANSO3A>2.0.ZU;2-Y
Abstract
A KDO synthesis is described using in the key step a potassic anion de rived from isopropyl dichloro or dibromoacetate, as an efficient equiv alent to install an alpha-ketoester unit onto a conveniently protected D-mannose.