AN UNEXPECTED STEREOCHEMICAL CONTROL OF ALKENE FORMATION BY THE CHOICE OF RADICAL INITIATOR - THE REVERSIBLE ADDITION OF (ME3SI)3SI. RADICALS TO ALKENES

Authors
FERRERI C BALLESTRI M CHATGILIALOGLU C
Citation
C. Ferreri et al., AN UNEXPECTED STEREOCHEMICAL CONTROL OF ALKENE FORMATION BY THE CHOICE OF RADICAL INITIATOR - THE REVERSIBLE ADDITION OF (ME3SI)3SI. RADICALS TO ALKENES, Tetrahedron letters, 34(32), 1993, pp. 5147-5150
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
32
Year of publication
1993
Pages
5147 - 5150
Database
ISI
SICI code
0040-4039(1993)34:32<5147:AUSCOA>2.0.ZU;2-4
Abstract
Tris(trimethylsilyl)silyl radical is effective in isomerizing some (Z) -olefins into their thermodynamically more stable (E)-isomers by an ad dition-elimination path.