SYNTHESIS AND STRUCTURE OF HYLIDEN-2,4,6-TRIMETHYLANILINE(N,C)-PALLADIUM(II)]

Authors
BLANCO J GAYOSO E VILA JM GAYOSO M
Citation
J. Blanco et al., SYNTHESIS AND STRUCTURE OF HYLIDEN-2,4,6-TRIMETHYLANILINE(N,C)-PALLADIUM(II)], Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 48(7), 1993, pp. 906-910
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
48
Issue
7
Year of publication
1993
Pages
906 - 910
Database
ISI
SICI code
0932-0776(1993)48:7<906:SASOH>2.0.ZU;2-D
Abstract
Reaction of Na2PdCl4 with N-ferrocenylmethylidene-2,4,6-trimethylanili ne yields the dimeric, chloro-bridged Pd(II) complex [Pd {(C5H5)FeC5H3 C(H) = N-2,4,6-(CH3)3C6H2}Cl]2. The title complex (1) is obtained by s ubstitution of the chloro-bridges with acetate. 1 crystallizes in the orthorhombic space group Pbca with the lattice parameters a = 1346.4(4 ), b = 2876.6(2), c = 2472.8(5) pm and Z = 8. In the dimeric complex e ach Pd2+ cation exhibits a square-planar coordination by the N atom an d an ortho-C atom of the cyclopentadienyl ring of the Schiff-base and two oxygen atoms of two different bridging acetato groups.