OXA-AZONIA-BORATACYCLOPENTANES BY INSERTION OF DIMETHYLAMINOBIS(TRIFLUOROMETHYL)BORANE INTO EPOXIDES

Authors
BURGER H HAGEN T PAWELKE G
Citation
H. Burger et al., OXA-AZONIA-BORATACYCLOPENTANES BY INSERTION OF DIMETHYLAMINOBIS(TRIFLUOROMETHYL)BORANE INTO EPOXIDES, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 48(7), 1993, pp. 935-939
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
48
Issue
7
Year of publication
1993
Pages
935 - 939
Database
ISI
SICI code
0932-0776(1993)48:7<935:OBIOD>2.0.ZU;2-T
Abstract
Dimethylaminobis(trifluoromethyl)borane, (CF3)2BNMe2 (A). reacts with epoxides of the general formula O-CH2-CHR to yield five-membered heter ocycles (CF3)2B-NMe2-CH2-CHR-O, R = Me (1), CH2F (2), CF, (3), Et (4), Bz (5). With R - Ph a 1:2 mixture of the isomers (CF3)2B-NMe2-CH2-CHP h-O (6a) and (CF3)2B-NMe2-CHPh-CH2-O (6b) is obtained. To the contrary , O-CH2-CMe2 and A form the borane-dimethylamine adduct (H2C=CMe-CH2-O )(CF3)2B.NHMe2 (7). The compounds have been characterized by elemental analyses, multinuclear NMR, IR and mass spectra.