SYNTHESIS AND MOLECULAR-STRUCTURE OF ALME[O=C(OME)C6H4-O-O]2 - THE 1ST STRUCTURALLY CHARACTERIZED 5-COORDINATED SIMPLE ALKYLALUMINUM CHELATE COMPLEX

Authors
LEWINSKI J ZACHARA J MANK B PASYNKIEWICZ S
Citation
J. Lewinski et al., SYNTHESIS AND MOLECULAR-STRUCTURE OF ALME[O=C(OME)C6H4-O-O]2 - THE 1ST STRUCTURALLY CHARACTERIZED 5-COORDINATED SIMPLE ALKYLALUMINUM CHELATE COMPLEX, Journal of organometallic chemistry, 454(1-2), 1993, pp. 5-7
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
454
Issue
1-2
Year of publication
1993
Pages
5 - 7
Database
ISI
SICI code
0022-328X(1993)454:1-2<5:SAMOA->2.0.ZU;2-A
Abstract
The interaction of AlMe3 with 2 equiv. of O=C(OMe)C6H4-o-OH leads to t he formation of the mononuclear, five-coordinated aluminium compound A lMe[O=C(OMe)C6H4-o-0]2. The title compound has been characterized by I R, H-1 and Al-27 NMR spectroscopies and its structure has been confirm ed by X-ray crystallography. The compound crystallizes in the monoclin ic space group C2/c with the unit cell parameters a = 16.144(2), b = 7 .703(1), c = 14.792(2) angstrom, beta = 112.76(l)-degrees, Z = 4, obse rved data = 1060, R = 0.0380, R(w) = 0.0378.