A COMPLEX SALT FORMED IN REACTIONS OF NBUSNCL3 WITH -(2-METHYL-2,3-DIHYDROBENZOTHIAZOL-2-YL)-2-KETONES

Authors
TEO SB TEOH SG OKECHUKWU RC FUN HK
Citation
Sb. Teo et al., A COMPLEX SALT FORMED IN REACTIONS OF NBUSNCL3 WITH -(2-METHYL-2,3-DIHYDROBENZOTHIAZOL-2-YL)-2-KETONES, Journal of organometallic chemistry, 454(1-2), 1993, pp. 67-71
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
454
Issue
1-2
Year of publication
1993
Pages
67 - 71
Database
ISI
SICI code
0022-328X(1993)454:1-2<67:ACSFIR>2.0.ZU;2-T
Abstract
The reaction of nBuSnCl3 With 142-methyl-2,3-dihydrobenzothiazol-2-yl) -2-ketones (ketone = propanone, methyl phenyl ketone) involves cleavag e of the exocyclic ketonyl group to give the complex salt [(C8H8NS)+]2 [(C4H9Sn(OH)C]3)2]2-. 2[C8H7NS]. An X-ray diffraction study of the com plex has revealed the first example of true hydrogen bonding involving an Sn-Cl bond.