Citation
Ld. Field et Av. George, THE USE OF HIGH REACTION PRESSURES IN THE SYNTHESIS OF ACETYLIDE COMPLEXES OF IRON, Journal of organometallic chemistry, 454(1-2), 1993, pp. 217-219
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
0022328X
Volume
454
Issue
1-2
Year of publication
1993
Pages
217 - 219
Database
ISI
SICI code
0022-328X(1993)454:1-2<217:TUOHRP>2.0.ZU;2-E
Abstract
High pressures (100-800 MPa) have been used to assist the synthesis of
acetylide complexes of iron. The complex FeH(C=CPh)(dmpe)2 (dmpe = 1,
2-bis(dimethylphosphino)ethane) was formed quantitatively in 30 min fr
om the reaction of FeH2(dmpe)2 with phenylacetylene in toluene under a
pressure of 800 MPa.