We have determined the distribution of n states initially populated in
a double- or multielectron-capture collision of Kr(q+) (q = 17,18) wi
th Kr at low energy (almost-equal-to 5 keV/u). Radiative decay curves
of Rydberg transitions of the projectile ions were obtained by transla
ting the target gas jet along the projectile beam. As a result for Kr1
8+ projectiles, we found that an initial population of Kr16+ equally d
istributed from n = 14 to 19 allows the observed Kr XVII 13-14 radiati
ve decay curve to be reproduced relatively well. Furthermore, coincide
nce time-of-flight spectroscopy of photons emitted by recoil ions of g
iven charge states was used to measure the radiative decay of recoil-i
on transitions. From the Kr VII 7i-8k decay curve we deduced an initia
l population distribution of the Kr6+ recoil ion centered around n=20.
These results lead to a better understanding of the mechanisms of dou
ble-electron capture responsible for populating Rydberg states, especi
ally those in asymmetric configurations.