Nh. Lajis et al., EPI-SARSASAPOGENIN AND EPI-SMILAGENIN - 2 SAPOGENINS ISOLATED FROM THE RUMEN CONTENT OF SHEEP INTOXICATED BY BRACHIARIA-DECUMBENS, Steroids, 58(8), 1993, pp. 387-389
Spectroscopic examination of purified extracts of the rumen content of
sheep intoxicated by Brachiaria decumbens revealed the presence of tw
o spirostanes, identified as epi-sarsasapogenin and epi-smilagenin. Sa
rsasapogenone was obtained by the oxidation of sarsasapogenin. The red
uction of sarsasapogenone using lithium aluminum hydride yielded isome
ric products, sarsasapogenin (20%) and episarsasapogenin (80%).