Sr. Nutt et P. Lipetzky, CREEP DEFORMATION OF WHISKER-REINFORCED ALUMINA, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 166(1-2), 1993, pp. 199-209
The creep behavior of alumina reinforced with SiC whiskers was studied
under different loading geometries and test ambients. Deformed micros
tructures were examined and characterized to ascertain mechanisms of d
eformation and damage, and to understand better the causes of the meas
ured creep response. The composites undergo creep by grain boundary sl
iding that is generally accommodated by diffusion, although high stres
ses and temperatures lead to increasing degrees of creep damage in the
form of cavitation at interfaces and grain boundaries. Creep rates de
crease with increasing whisker volume fraction as whiskers increasingl
y inhibit grain boundary sliding. In aerobic test atmospheres, the com
posites undergo a thermal oxidation reaction that generates glassy fil
ms at internal boundaries and carbon monoxide gas, both of which facil
itate cavitational damage. Systematic study of the thermal oxidation r
eaction in the absence of stress shows that oxidation occurs at interf
aces, generating silica glass and graphitic carbon via a ''carbon-cond
ensed'' oxidation displacement reaction.