The formation of the Fe/MnO interface at room temperature has been stu
died for iron coverages in the range 1-8 angstrom by synchrotron radia
tion induced photoemission spectroscopy. The valence band and 3p and 3
s core levels of both Fe and Mn were recorded after each metal evapora
tion. At first, strong interaction between iron and the substrate is o
bserved with Fe2+ and Fe3+ oxide formation. By increasing the coverage
the diffusion of Fe(O) at the interface seems to take place simultane
ously with the growth of an upper metallic Fe layer.