Ga. Mattiussi et al., EXPOSURE OF ADVANCED POSITIVE AND NEGATIVE E-BEAM RESISTS WITH FOCUSED ION-BEAMS, Journal of the Electrochemical Society, 140(8), 1993, pp. 2332-2338
Negative- and positive-tone e-beam resists have been exposed by focuse
d beams of Si++ and Be++ ions. The resolution of the negative resist.
Shipley SAL601-ER7, was better than 0.2 mum and vertical sidewalls wer
e achieved. A dose of 2 X 10(12) ions cm-3 was required to retain the
full thickness of the resist after developing. Different postexposure
bake (PEB) times and temperatures were examined in this work. A satura
tion in resist response was observed at moderately high PEB temperatur
es 115-125-degrees-C). This effect has not been reported previously fo
r either ion-beam or e-beam exposure. Increases in developing time can
increase the sensitivity and the effective contrast of this resist. T
he positive-tone resist, OCG Microelectronic Materials P28, is at leas
t two to three times more sensitive than PMMA. It also displays a wide
range of doses (4-25 X 10(12) ions cm-2) for which positive-tone imag
ing is possible. Present results show the resolution of P28 to be at l
east 0.3 mum, which is not as fine as that of polymethylmethacrylate (
PMMA). Preliminary results on the behavior of the P28 resist as a mask
for silicon etching are presented.