THE ELECTRIC-DIPOLE MOMENT OF (NH3)2 FOR G - VERTICAL-BAR-K-VERTICAL-BAR=1

Citation
H. Linnartz et al., THE ELECTRIC-DIPOLE MOMENT OF (NH3)2 FOR G - VERTICAL-BAR-K-VERTICAL-BAR=1, The Journal of chemical physics, 99(4), 1993, pp. 2449-2452
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
99
Issue
4
Year of publication
1993
Pages
2449 - 2452
Database
ISI
SICI code
0021-9606(1993)99:4<2449:TEMO(F>2.0.ZU;2-E
Abstract
From the results of Stark measurements on the (NH3)2 van der Waals com plex formed in a molecular jet expansion, it was possible to determine the electric dipole moment for the G: Absolute value of K = 1 state. The partially quenched inversion in the complex gives rise to quadrati c Stark effect. We find an electric dipole moment of Absolute value of mu = (0. 10 +/- 0.01) D in the ground state and an upper limit of 0.0 9 D for the dipole moment in the excited state. These small values giv e evidence that for the G: Absolute value of K = 1-1 states, the ''ant iparallel'' (cyclic) structure is more likely than the hydrogen bonded one.