THE CORRESPONDENCE BETWEEN CLASSICAL NONLINEAR RESONANCES AND QUANTUM-MECHANICAL FERMI RESONANCES

Citation
Fl. Roberts et C. Jaffe, THE CORRESPONDENCE BETWEEN CLASSICAL NONLINEAR RESONANCES AND QUANTUM-MECHANICAL FERMI RESONANCES, The Journal of chemical physics, 99(4), 1993, pp. 2495-2505
Citations number
36
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
99
Issue
4
Year of publication
1993
Pages
2495 - 2505
Database
ISI
SICI code
0021-9606(1993)99:4<2495:TCBCNR>2.0.ZU;2-X
Abstract
The correspondence between classical nonlinear resonances and quantum mechanical Fermi resonances is discussed. The principle result is the recognition that the classical resonant behavior does not contribute t o the diagonal matrix elements, but rather contributes to the off-diag onal matrix elements. As a direct consequence, it is not necessary for the classical dynamics corresponding to the quantum mechanical states involved in a Fermi resonance to exhibit resonant behavior. Instead, it is the classical dynamics associated with the matrix element which connects the quantum mechanical states involved in the Fermi resonance which must exhibit resonant behavior. These results are illustrated n umerically using a very simple model of two kinetically coupled Morse oscillators.