Fl. Roberts et C. Jaffe, THE CORRESPONDENCE BETWEEN CLASSICAL NONLINEAR RESONANCES AND QUANTUM-MECHANICAL FERMI RESONANCES, The Journal of chemical physics, 99(4), 1993, pp. 2495-2505
The correspondence between classical nonlinear resonances and quantum
mechanical Fermi resonances is discussed. The principle result is the
recognition that the classical resonant behavior does not contribute t
o the diagonal matrix elements, but rather contributes to the off-diag
onal matrix elements. As a direct consequence, it is not necessary for
the classical dynamics corresponding to the quantum mechanical states
involved in a Fermi resonance to exhibit resonant behavior. Instead,
it is the classical dynamics associated with the matrix element which
connects the quantum mechanical states involved in the Fermi resonance
which must exhibit resonant behavior. These results are illustrated n
umerically using a very simple model of two kinetically coupled Morse
oscillators.