SYNTHESIS, STRUCTURE, AND DYNAMICS OF ENDO-(STARPHENYLENE)CHROMIUM TRICARBONYL DERIVATIVES - OBSERVATION OF METAL ARENE MIGRATION AND HINDERED METAL-TRIPOD ROTATION

Authors
NAMBU M MOHLER DL HARDCASTLE K BALDRIDGE KK SIEGEL JS
Citation
M. Nambu et al., SYNTHESIS, STRUCTURE, AND DYNAMICS OF ENDO-(STARPHENYLENE)CHROMIUM TRICARBONYL DERIVATIVES - OBSERVATION OF METAL ARENE MIGRATION AND HINDERED METAL-TRIPOD ROTATION, Journal of the American Chemical Society, 115(14), 1993, pp. 6138-6142
Citations number
39
Categorie Soggetti
Chemistry
Journal title
Journal of the American Chemical Society → ACNP
ISSN journal
00027863
Volume
115
Issue
14
Year of publication
1993
Pages
6138 - 6142
Database
ISI
SICI code
0002-7863(1993)115:14<6138:SSADOE>2.0.ZU;2-N
Abstract
The dynamic stereochemistry of endo-(starphenylene)chromium tricarbony l, endo-1-Cr, is elucidated through NMR spectroscopic methods. Intramo lecular metal-arene migration and hindered metal-tripod rotation are o bserved in closely related derivatives of endo-1-Cr. The stereochemist ry of these systems is modeled well by ab initio local density functio nal theory methods.