S. Rengamani et al., BETA-PHENYLETHYLAMINE AS AN INHIBITOR FOR CORROSION OF MILD-STEEL IN ACIDIC SOLUTIONS, Indian Journal of Technology, 31(7), 1993, pp. 519-524
Beta-phenylethylamine (BPEA) is found to be a better inhibitor in 1N H
Cl than in 1N H2SO4. Capillary electrometer studies show that the adso
rption of the inhibitor is more from HCl, than from H2SO4. Hydrogen pe
rmeation and impedance measurements also indicate improved performance
of the inhibitor in HCl Galvanostatic polarisation studies show BPEA
to be a cathodic inhibitor. Surface examination by UV reflectance spec
troscopy and scanning electron microscopy clearly shows that the inhib
ition is due to a polymolecular film formed by the physical adsorption
of the inhibitor on the metal surface.