A SOLID SULFUR CATHODE FOR AQUEOUS BATTERIES

Because of its high resistivity and subsequent low electroactivity, su lfur is not normally considered a room-temperature battery cathode. An elemental sulfur cathode has been made with a measured capacity of ov er 900 ampere.hours per kilogram, more than 90 percent of the theoreti cal storage capacity of solid sulfur at room temperature, accessed by means of a lightweight, highly conductive, aqueous polysulfide interfa ce through the electrocatalyzed reaction S + H2O + 2e- --> HS- + OH-. This solid sulfur cathode was first used in a battery with an aluminum anode for an overall discharge reaction 2Al + 3S + 3OH- + 3H2O --> 2A l(OH)3 + 3HS-, giving a cell potential of 1.3 volts. The theoretical s pecific energy of the aluminum-sulfur battery (based on potassium salt s) is 910 watt.hours per kilogram with an experimental specific energy of up to 220 waft.hours per kilogram.