NOVEL SYNTHESES OF HETERODINUCLEAR PHOSPHAALKENYL COMPLEXES - X-RAY STRUCTURE OF [RU(P(AUPPH(3))=CHBU(T))CL-2(CO)(PPH(3))(2)]

Authors
BEDFORD RB HILL AF JONES C WHITE AJP WILLIAMS DJ WILTONELY JDET
Citation
Rb. Bedford et al., NOVEL SYNTHESES OF HETERODINUCLEAR PHOSPHAALKENYL COMPLEXES - X-RAY STRUCTURE OF [RU(P(AUPPH(3))=CHBU(T))CL-2(CO)(PPH(3))(2)], Chemical communications, (2), 1997, pp. 179-180
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1997
Pages
179 - 180
Database
ISI
SICI code
1359-7345(1997):2<179:NSOHPC>2.0.ZU;2-I
Abstract
The reaction of [Ru(P=CHBu(t))Cl(CE)(PPh(3))(2)] (E = O, S) with [AuX( PPh(3))] (X = Cl, C=CC(6)H(4)Me-4), HgCl2 or Hg2Cl2 leads via addition of the Au-X or Hg-Cl bonds across the Ru-P linkage to the heterodinuc lear phosphaalkene complexes [Ru{P(AuPPh(3))=CHBu(t)}ClX(CE)(PPh(3))(2 )] and [Ru{P(HgCl)=CHBu(t)}Cl-2(CE)(PPh(3))(2)].