SHAPING THE CAVITY OF CALIX[4]ARENE USING TRANSITION-METALS AND BINDING ALKALI-METAL CATIONS INSIDE THE CAVITY - THE RELEVANCE OF THE ALKALI-METAL CATION-ARENE INTERACTION

Authors
ZANOTTIGEROSA A SOLARI E GIANNINI L FLORIANI C CHIESIVILLA A RIZZOLI C
Citation
A. Zanottigerosa et al., SHAPING THE CAVITY OF CALIX[4]ARENE USING TRANSITION-METALS AND BINDING ALKALI-METAL CATIONS INSIDE THE CAVITY - THE RELEVANCE OF THE ALKALI-METAL CATION-ARENE INTERACTION, Chemical communications, (2), 1997, pp. 183-184
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1997
Pages
183 - 184
Database
ISI
SICI code
1359-7345(1997):2<183:STCOCU>2.0.ZU;2-0
Abstract
Transition metals can be used for shaping and electronically enriching the calix[4]arene cavity; in this approach, the pi-basic cavities can be adapted to alkali-metal cation complexation in a very hydrophobic environment and these cations can even be transferred into aliphatic h ydrocarbons; the eta(6)-arene-alkali-metal cation interaction is struc turally elucidated.