TRIGOLD TRIACETYLIDES - POLYMERIZATION THROUGH GOLD-CENTER-DOT-CENTER-DOT-CENTER-DOT-GOLD BONDING OR BRIDGING LIGANDS

Authors
IRWIN MJ MANOJLOVICMUIR L MUIR KW PUDDEPHATT RJ YUFIT DS
Citation
Mj. Irwin et al., TRIGOLD TRIACETYLIDES - POLYMERIZATION THROUGH GOLD-CENTER-DOT-CENTER-DOT-CENTER-DOT-GOLD BONDING OR BRIDGING LIGANDS, Chemical communications, (2), 1997, pp. 219-220
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1997
Pages
219 - 220
Database
ISI
SICI code
1359-7345(1997):2<219:TT-PTG>2.0.ZU;2-B
Abstract
The new trigold(I) triacetylide [C6H3(C=CAu)(3)-1,3,5] reacts with mon odentate ligands, L = isocyanide, phosphite or phosphine, to give [C6H 3(C=C AuL)(3)-1,3,5] complexes which form polymeric solids with interm olecular Au Au bonding; it also reacts with bidentate ligands to give covalently linked network polymers of the formula [{C6H3(C=C AU)(3)-1, 3,5}(2)(mu-L-L)(3)], L-L = diisocyanide or diphosphine.