A NOVEL DIAMINOBORATE LIGAND SYSTEM DERIVED FROM 1,8-DIAMINONAPHTHALENE AND 9-BBN - PREPARATION OF TITANIUM AND ZIRCONIUM COMPLEXES AND CRYSTAL-STRUCTURE OF THE TITANIUM COMPLEX

Authors
BARHAIM G SHACH R KOL M
Citation
G. Barhaim et al., A NOVEL DIAMINOBORATE LIGAND SYSTEM DERIVED FROM 1,8-DIAMINONAPHTHALENE AND 9-BBN - PREPARATION OF TITANIUM AND ZIRCONIUM COMPLEXES AND CRYSTAL-STRUCTURE OF THE TITANIUM COMPLEX, Chemical communications, (2), 1997, pp. 229-230
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
2
Year of publication
1997
Pages
229 - 230
Database
ISI
SICI code
1359-7345(1997):2<229:ANDLSD>2.0.ZU;2-G
Abstract
1,8-Diaminonaphthalene reacts selectively with 1 equiv. of 9-BBN to fo rm a bridging amine-aminoborane, and with 2 equiv. of 9-BBN to form a non-bridging bis(aminoborane); these aminoboranes give rise to a novel diaminoborate (4e,1-) ligand system by reactions with dimethylamides of titanium and zirconium.