AN EXAFS STUDY OF GRIGNARD COMPOUNDS IN SOLUTION

Authors
ERTEL TS BERTAGNOLLI H
Citation
Ts. Ertel et H. Bertagnolli, AN EXAFS STUDY OF GRIGNARD COMPOUNDS IN SOLUTION, Polyhedron, 12(18), 1993, pp. 2175-2184
Citations number
65
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
18
Year of publication
1993
Pages
2175 - 2184
Database
ISI
SICI code
0277-5387(1993)12:18<2175:AESOGC>2.0.ZU;2-0
Abstract
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide in diethyl ether and vinyl magnesium brom ide in tetrahydrofuran are presented in this paper. The degree of mole cular association and the local structure around the central magnesium atoms are deduced from the determined distances and coordination numb ers.