THERMODYNAMIC INTERACTIONS IN BINARY-MIXTURES OF 2-METHOXYETHANOL WITH ALKYL AND ARYL ESTERS AT 298.15-K, 303.15-K AND 308.15-K

Citation
Tm. Aminabhavi et Sk. Raikar, THERMODYNAMIC INTERACTIONS IN BINARY-MIXTURES OF 2-METHOXYETHANOL WITH ALKYL AND ARYL ESTERS AT 298.15-K, 303.15-K AND 308.15-K, Collection of Czechoslovak Chemical Communications, 58(8), 1993, pp. 1761-1776
Citations number
21
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
58
Issue
8
Year of publication
1993
Pages
1761 - 1776
Database
ISI
SICI code
0010-0765(1993)58:8<1761:TIIBO2>2.0.ZU;2-Q
Abstract
Densities, viscosities, refractive indices, and sound velocities of 2- methoxyethanol + ester mixtures have been measured at 298.15, 303.15 a nd 308.15 K. These data have been used to calculate excess volume, exc ess isentropic compressibility, excess refraction, excess viscosity an d excess Gibbs energy of activation of flow. These quantities have bee n fitted to quadratic equations to estimate the parameters and standar d errors. The results have been interpreted in terms of the intermolec ular interactions between the mixing components.