L. Medvecky et al., MODIFICATION OF CLINOPTILOLITE BY SYNTHETIC ZEOLITE, Collection of Czechoslovak Chemical Communications, 58(8), 1993, pp. 1782-1790
The sol-gel process allows to modify clinoptilolite by the nucleation
of synthetic zeolite. From the viewpoint of methanol conversion, the o
btained high Al content nucleation-deposited zeolite decreases the cat
alytic activity of clinoptilolite. Therefore, it is necessary to optim
ize the selection of suitable synthetic zeolite as to its composition.
Contamination of zeolite surfaces by carbonaceous fragments during ca
talytic process results from physico-chemical characteristics of the u
sed and processed zeolite, and according to DTA and TG analysis it sig
nificantly affects the readsorption of water vapours and likely also t
he zeolite activity in methanol conversion.