MODIFICATION OF CLINOPTILOLITE BY SYNTHETIC ZEOLITE

Citation
L. Medvecky et al., MODIFICATION OF CLINOPTILOLITE BY SYNTHETIC ZEOLITE, Collection of Czechoslovak Chemical Communications, 58(8), 1993, pp. 1782-1790
Citations number
7
Categorie Soggetti
Chemistry
ISSN journal
00100765
Volume
58
Issue
8
Year of publication
1993
Pages
1782 - 1790
Database
ISI
SICI code
0010-0765(1993)58:8<1782:MOCBSZ>2.0.ZU;2-M
Abstract
The sol-gel process allows to modify clinoptilolite by the nucleation of synthetic zeolite. From the viewpoint of methanol conversion, the o btained high Al content nucleation-deposited zeolite decreases the cat alytic activity of clinoptilolite. Therefore, it is necessary to optim ize the selection of suitable synthetic zeolite as to its composition. Contamination of zeolite surfaces by carbonaceous fragments during ca talytic process results from physico-chemical characteristics of the u sed and processed zeolite, and according to DTA and TG analysis it sig nificantly affects the readsorption of water vapours and likely also t he zeolite activity in methanol conversion.