REGIOSELECTIVE SYNTHESIS OF PHOTOLABILE P(1,2)-(O-NITROBENZYL) AND P(4,5)-(O-NITROBENZYL) ESTERS OF MYOINOSITOL 1,2,3,4,5,6-HEXAKISPHOSPHATE

Authors
CHEN JA PRESTWICH GD
Citation
Ja. Chen et Gd. Prestwich, REGIOSELECTIVE SYNTHESIS OF PHOTOLABILE P(1,2)-(O-NITROBENZYL) AND P(4,5)-(O-NITROBENZYL) ESTERS OF MYOINOSITOL 1,2,3,4,5,6-HEXAKISPHOSPHATE, Tetrahedron letters, 38(6), 1997, pp. 969-972
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
6
Year of publication
1997
Pages
969 - 972
Database
ISI
SICI code
0040-4039(1997)38:6<969:RSOPPA>2.0.ZU;2-J
Abstract
The regioselective synthesis of four caged InsP(6) derivatives is desc ribed. The synthesis employed allyl ester protecting groups, and Rh(I) could selectively deprotect all allyl phosphates in a single step wit hout affecting the photolabile moieties. (C) 1997, Elsevier Science Lt d.