CR(CO)(3)-COMPLEXED BENZYLPHOSPHONATES - A HORNER-EMMONS-WADSWORTH APPROACH TO ALKENYL SUBSTITUTED TRICARBONYLCHROMIUM ARENE COMPLEXES

Authors
MULLER TJJ
Citation
Tjj. Muller, CR(CO)(3)-COMPLEXED BENZYLPHOSPHONATES - A HORNER-EMMONS-WADSWORTH APPROACH TO ALKENYL SUBSTITUTED TRICARBONYLCHROMIUM ARENE COMPLEXES, Tetrahedron letters, 38(6), 1997, pp. 1025-1028
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
6
Year of publication
1997
Pages
1025 - 1028
Database
ISI
SICI code
0040-4039(1997)38:6<1025:CB-AHA>2.0.ZU;2-D
Abstract
The Horner-Emmons-Wadsworth reaction of eta(6)-benzylphosphonate compl exes 1 with aldehydes, dialdehydes and ketones 2 with sodium hydride a s a base in boiling THF gives rise to areneCr(CO)(3) substituted trans -alkenes 3 in moderate to good yields. (C) 1997, Elsevier Science Ltd.