REGIOSELECTIVITY IN THE ENE REACTION OF SINGLET OXYGEN WITH ALKENES BEARING AN ELECTRON-WITHDRAWING GROUP AT BETA-POSITION

Authors
STRATAKIS M ORFANOPOULOS M
Citation
M. Stratakis et M. Orfanopoulos, REGIOSELECTIVITY IN THE ENE REACTION OF SINGLET OXYGEN WITH ALKENES BEARING AN ELECTRON-WITHDRAWING GROUP AT BETA-POSITION, Tetrahedron letters, 38(6), 1997, pp. 1067-1070
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
6
Year of publication
1997
Pages
1067 - 1070
Database
ISI
SICI code
0040-4039(1997)38:6<1067:RITERO>2.0.ZU;2-H
Abstract
Electronic repulsions between a perepoxide intermediate and the allyli c functionality in the product forming transition state, direct the re gioselectivity in the photooxygenation of trisubstituted alkenes beari ng an electron withdrawing group at beta- position. (C) 1997, Elsevier Science Ltd.