MASS-SPECTRA OF SOME PHENYLPHOSPHINOSILANES

Authors
KIM TW JAHNG WS KIM CH LEE ME
Citation
Tw. Kim et al., MASS-SPECTRA OF SOME PHENYLPHOSPHINOSILANES, Rapid communications in mass spectrometry, 7(10), 1993, pp. 898-901
Citations number
15
Categorie Soggetti
Spectroscopy,"Chemistry Analytical
Journal title
Rapid communications in mass spectrometry → ACNP
ISSN journal
09514198
Volume
7
Issue
10
Year of publication
1993
Pages
898 - 901
Database
ISI
SICI code
0951-4198(1993)7:10<898:MOSP>2.0.ZU;2-3
Abstract
The 70 eV electron-impact low resolution spectra of Me3SiPPh2, (Me3Si) 3SiPPh2, and (Me3Si)2(Me)SiP(Me)(Ph) were investigated. The migration of two phenyl groups from phosphorous to a silicon site was observed a nd the unimolecular mass-analysed ion kinetic energy spectra indicated that the migration occurred in [M - CH3]+ ions rather than in M+. ion s. The benzene eliminations from the M+. and [M-CH3]+ ions of Me3SiPPh 2 were observed not in the EI spectrum, but in their MIKE spectra.