Dp. Monaghan et al., DEPOSITION OF GRADED ALLOY NITRIDE FILMS BY CLOSED FIELD UNBALANCED MAGNETRON SPUTTERING, Surface & coatings technology, 59(1-3), 1993, pp. 21-25
The development of a deposition system based on closed field unbalance
d magnetron sputter ion plating (uniform deposition and plasma), has g
reatly increased the number of complex nitrides that it is possible to
routinely deposit. The new alloy nitrides can increase the hardness o
f standard TiN by a factor of 2, and can consequently result in longer
tool life, In order to maintain high levels of coating to substrate a
dhesion, it is necessary to gradually grade the composition of the fil
m in the interface region. Grading of an alloy nitride such as TiZrN w
ill ensure minimum L(c) scratch adhesion levels of 75 N. The technique
can be closely controlled and is very flexible, enabling the changes
in composition to be attained with precision.