HOMOGENEOUS ISOTOPE-EXCHANGE BETWEEN NICKEL(II) AND BIS(RESACETOPHENONE PHENYLHYDRAZONE) NICKEL(II) COMPLEX

Authors
GANGAIAH T RAMADEVI P BALAJI T NAIDU GRK
Citation
T. Gangaiah et al., HOMOGENEOUS ISOTOPE-EXCHANGE BETWEEN NICKEL(II) AND BIS(RESACETOPHENONE PHENYLHYDRAZONE) NICKEL(II) COMPLEX, Journal of radioanalytical and nuclear chemistry, 173(1), 1993, pp. 137-140
Citations number
9
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
173
Issue
1
Year of publication
1993
Pages
137 - 140
Database
ISI
SICI code
0236-5731(1993)173:1<137:HIBNAB>2.0.ZU;2-Z
Abstract
Isotope exchange behavior of bis-resacetophenone phenylhydrazone) nick el(II) complex with nickel(II) in tri-n-butyl phosphate and methanol m edium has been studied. The studies were carried out at different temp eratures varying the concentration of both metal ion and the complex. The results show that the complex is labile in the kinetic sense. Incr ease in temperature increases the isotope exchange rate. The increase in concentration also results in an enhancement of the rate of reactio n.