Kc. Hansen et al., DETERMINATION OF HENRY LAW CONSTANTS OF ORGANICS IN DILUTE AQUEOUS-SOLUTIONS, Journal of chemical and engineering data, 38(4), 1993, pp. 546-550
Henry's law constants of 15 volatile organic compounds in dilute aqueo
us solutions were measured by the procedure of equilibrium partitionin
g in a closed system. The method is based upon the measurement of the
headspace concentration by gas chromatography. The compounds investiga
ted included six halogenated hydrocarbons, four aromatic hydrocarbons,
and five alkanes. The measurements were made at three temperatures be
tween 25 and 45-degrees-C. The measured Henry's law constants compared
well with the literature data of some liquids. The temperature depend
ence of Henry's law constant was also studied from the van't Hoff rela
tion.